Oxidative dehydrogenation of propane over 3D printed mixed metal oxides/H-ZSM-5 monolithic catalysts using CO2 as an oxidant

نویسندگان

چکیده

The effect of Ga, V, and Zr content on the structural properties catalytic behavior H-ZSM-5 monolithic catalysts-supported gallium oxide, vanadium zirconium oxide in oxidative dehydrogenation propane (ODHP) have been investigated a continuous tubular microreactor using CO2 as mild oxidant. SEM-EDX confirmed homogeneous distribution metal oxides within printed oxide/H-ZSM-5 catalysts ODHP reaction was carried out absence (5 mol% propane, balanced with N2) presence (2.5 5 at 500, 550, 600, 650 ?, 1 bar, space velocity 4500 mL/gcat.hr. Among all synthesized Zr/H-ZSM-5 catalysts, [email protected] catalyst exhibits both high activity stability for conversion 38 % propylene selectivity 90 without any observable trend benzene, toluene, xylene (BTX) production deactivation 6 h time stream. catalyst’s is also enhanced by introduction CO2. In CO2, more coke formation observed which addition to reduced ?1?5 %.

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ژورنال

عنوان ژورنال: Catalysis Today

سال: 2021

ISSN: ['0920-5861', '1873-4308']

DOI: https://doi.org/10.1016/j.cattod.2020.10.002